Graphene supported hemin as a highly active biomimetic catalyst
T. Xue, S. Jiang, Y. Qu, Q. Su, R. Cheng, S. Dubin, C.-Y. Chiu, R. Kaner, Y. Huang and X. Duan
Angew. Chemie Intl. Ed. 51, 3725-3974 (2012)
Well supported: Stable hemin–graphene conjugates (see picture) formed by immobilization of monomeric hemin on graphene, showed excellent catalytic activity, more than 10 times better than that of the recently developed hemin–hydrogel system and 100 times better than that of unsupported hemin. The catalysts also showed excellent binding affinities and catalytic efficiencies approaching that of natural enzymes.